Organometallic Chemistry, Volume 27M. Green Royal Society of Chemistry, 1999 - 480 pagina's Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume. |
Inhoudsopgave
Complexes Containing MetalCarbon σBonds of the Groups | 1 |
Reviews and Articles of General Interest | 81 |
Carbene and Carbyne Compounds of Groups 8 9 and 10 | 116 |
Metal Carbonyls | 132 |
References | 144 |
OrganoTransition Metal Cluster Compounds | 151 |
Group 4 | 157 |
Group 9 | 185 |
Arenes | 294 |
Organic Aspects of Organometallic Chemistry | 309 |
Alkene Metathesis Reactions | 315 |
References | 326 |
Polymerization Catalysis | 339 |
Organometallic Chemistry of Group 15 Elements | 347 |
Carbaboranes Including Their Metal Complexes | 359 |
Boron Aluminium Gallium Indium and Thallium | 380 |
Group 11 | 191 |
Hydrocarbon Transition Metal πComplexes Other | 221 |
Complexes Containing Unconjugated Alkenes | 234 |
Complexes Containing Alkynes | 242 |
nC5H5 and ηArene Substituted Transition Metal | 271 |
Biscyclopentadienyl Compounds | 281 |
Indium | 408 |
Thallium | 414 |
Copper Silver and Gold | 427 |
Group 2 BeBa and Group 12 ZnHg | 435 |
References | 444 |
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Veelvoorkomende woorden en zinsdelen
A.L. Rheingold acid Acta addition adducts afforded alkene alkyl alkyne allyl Angew anion aryl atoms binuclear bridged C-H activation carbene complexes catalyst cationic Chem chemistry Chim chiral clusters complexes containing compounds Coord coordination crystal structure cyclopentadienyl Dalton Trans derivatives diene dimeric electron Engl ferrocene fluxional formation formed fragment gave give halide hydride hydrogen Inorg insertion interactions intermediate investigated isolated isomerisation isomers Lett ligand lithium metal carbonyl metal centre metallocene methyl mixture moiety molecular molecules NMR spectroscopy nucleophilic obtained Organome Organomet Organometallic Chemistry Organometallics oxidation oxidative addition Ph Ph phosphine PMe3 Polyhedron polymeric polymerisation PPh₂ PPh3 prepared presence protonation Raithby reaction reactivity reacts reagents reduction reported ring Ru Ru ruthenium shown SiMe3 solvent species structurally characterised substituted synthesis temperature Thermolysis transition metal Treatment vinyl X-ray crystallography X-ray diffraction X-ray diffraction study yield