Organometallic Chemistry: Volume 13Edward W. Abel, F. G. A. Stone Royal Society of Chemistry, 1985 - 491 pagina's Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume. |
Inhoudsopgave
By J L Wardell | 1 |
Bibliography | 8 |
Calcium and Barium | 14 |
Chapter 3 | 24 |
Preparations and Reactions of Organoborane Systems | 28 |
Physical Data | 34 |
Aluminium Gallium Indium and Thallium | 56 |
vii | 59 |
Substitution Reactions of Metal and Organometal Carbonyls with Group V | 187 |
Complexes containing MetalCarbon oBonds of the Groups Scandium to Manga | 214 |
Complexes containing MetalCarbon oBonds of the Groups Iron Cobalt | 236 |
Carbene and Carbyne Complexes of the Group VIII Metals | 254 |
Bibliography | 261 |
MetalHydrocarbon πComplexes other than Cyclopentadienyl and πArene | 271 |
Complexes Derived from Unconjugated Dienes | 279 |
E Complexes Derived from Acetylenes | 292 |
The Silicon Group | 83 |
Hydrides | 100 |
Phosphorus Arsenic Antimony and Bismuth Derivatives | 107 |
Sulphur Selenium and Tellurium Derivatives | 113 |
Arsenic Antimony and Bismuth | 133 |
Metal Carbonyls | 140 |
Cluster Carbonyls containing C N O or S | 144 |
Organometallic Compounds containing MetalMetal Bonds | 150 |
Cyclopentadienyl πArene and Related Complexes | 317 |
Monoπcyclopentadienylmetal Complexes | 318 |
Monoπarene metal Complexes | 327 |
Homogeneous Catalysis by TransitionMetal Complexes | 345 |
Oxidation Reactions | 370 |
Synthesis | 371 |
Organometallic Compounds in Biological Chemistry | 381 |
Structures of Organometallic Compounds determined by Diffraction Methods | 407 |
Overige edities - Alles bekijken
Veelvoorkomende woorden en zinsdelen
acid Acta Crystallogr addition adducts Akad alkene alkyl alkynes allyl Angew anions Anorg aryl atoms B.F.G.Johnson bond bridged carbaborane carbene carbon catalysed cation CH₂ characterised chelate Chem chemistry Chen Chim cleavage clusters Co₂ Commun complexes compounds CP₂ crystal structure Dalton Trans derivatives dimer dppe electron electrophilic Engl F.G.A.Stone Fe(CO Fe₂ formation formed give H₂ halides hydride hydroformylation hydrogenation ibid Inorg insertion isomerisation isomers J.L.Atwood J.Lewis ketones Khim ligand M.Green M(CO metal carbonyls methyl Mo₂ Naturforsch Nauk SSSR nucleophilic Organomet Organometallics oxidation oxidative addition P.R.Raithby Ph₂ phosphine photolysis PMe3 Polyhedron PPh₂ PPh3 prepared presence protonation pyridine R=Me radical Re₂ reaction reactivity reacts reagents reduction reported Rh₂ rhodium ring Ru₂ silyl species spectra spectroscopic studies substituted Synth synthesis Teil Tetrahedron Lett thermal transition metal undergoes X-ray yields