The Porphyrin Handbook: Phthalocyanines: SynthesisKarl Kadish, Roger Guilard, Kevin M. Smith Elsevier, 2 dec 2012 - 369 pagina's The Porphyrin Handbook, Volume 15: Phthalocyanines: Synthesis provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the importance of compounds such as heme and chlorophyll that play vital roles in the biological systems responsible for the transportation of oxygen to cells in the body. This text then explores the different methods used for the preparation of phthalocyanine and its metallated derivatives. Other chapters consider the detailed survey of phthalocyanine formation, characterization, and purification. This book discusses as well the synthesis of low-symmetry phthalocyanines and related compounds. The final chapter deals with a survey of the structure, synthesis, and physiochemical properties of porphyrazines with annulated heterocycles. This book is a valuable resource for research scientists, engineers, and clinicians. |
Inhoudsopgave
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Chapter 98 The Synthesis of Symmetrical Phthalocyanines | 61 |
Chapter 99 Design and Synthesis of LowSymmetry Phthalocyanines and Related Systems | 125 |
Chapter 100 Synthesis and Spectroscopic Properties of Phthalocyanine Analogs | 161 |
Veelvoorkomende woorden en zinsdelen
1-chloronaphthalene absorption Abstr acid AcOH Ag/AgCl alkyl annulated aromatic atoms Bekaroglu benzene CDCl3 CF3COOH Chapter CHCl2 CHCl3 Chem Co(II CoCl2 complexes compounds condensation corresponding Cu(II CuCN cyanine cyclotetramerization derivatives diiminoisoindoline dinitrile DMAE DMSO electronic Figure formation groups H2 PcH2 Pn H2PC Hanack heterocycles Inorg isoindole isoindoline isomers Khim Kobayashi Lett Leznoff ligand Linstead Luk’yanets macrocycle meso-nitrogen metal-free method mixture molecule Ni(II nitrile nucleophilic obtained oxidation PCCO PcCu Pn PcH2 XII PcLi2 PcNi Pn pentan-1-ol pentanol phthalic phthalic acid phthalimide phthalo phthalocyanine phthalonitriles Pn VI NiCl2 Pn VII porphyrazine Porphyrins Porphyrins Phthalocyanines precursors prepared presence protons pyrazine pyridine pyrrole Q-band quinoline reaction Reagents redox reflux Scheme solubility solvent species starting material structure SubPc substituted synthesis t-Bu Table Torres trichlorobenzene Unsymmetrical urea UV-Vis spectra yield Zn PCZn Pn Zn(II ZnPc